Black Oxides


Black Oxide Finish for Stainless Steel

Blackon – SS-C is a blackening process that produces a black oxide finish on a variety of stainless steels, cast iron as well as mild steel low carbon steels. The coating produced with Blackon SS-C complies with military specifictionDTL-13924D, Class 4 and MIL C 13924.

  • Pleasing decorative black finish.
  • Powder used at 570 g/l in water.
  • Very economical black chemical conversion finish.
  • Chromium Free.
  • One powdered component blackening process.
  • Black oxide finish has good wear resistance and excellent adhesion.
  • RoHS and REACH compliant.
  • Produces a black oxide finish on a variety of stainless steels, cast iron as well as most mild steel low carbon steels
Typical Applications
  • Fasteners
  • Arms bluing
  • Automotive
  • Black body heat absorption
  • Non-reflective optics

Warranty and Disclaimer: This information is based on our experience and is, to the best of our knowledge, true and accurate. MAR-Tech Holdings Inc. gives no warranty, expressed or implied and the products are sold upon condition that the purchasers will make their own tests to determine the quality and suitability of the product. Any information or suggestions are given without warranty of any kind and the purchasers are solely responsible any loss arising from the use of such information.

  • Tanks: Mild steel tanks are required.

  • Heating and Cooling: Gas heating units are preferred for quickest heat up and temperature recovery when a load is introduced into the solution. Electric immersion heaters may be used but care should be taken to avoid scorching the solution by providing enough heaters to evenly heat the solution. 0.317 KW will be required per gallon of solution for a two-hour heat up time.

    An automatic indicating temperature control should be used to control a 1/4 inch electric operated water inlet valve.

  • Agitation: Mechanical agitation should be used during heat up to avoid local over-heating that will produce a loose red oxide on the parts.

  • Ventilation: Required.

Water must not be allowed to enter tank unless solution is boiling or is being stirred.

Required Inventory
  • Blackon - SS: Component used for make up and replenishment.

Operating Conditions:
  • Blackon - SS: 570 - 600 g/L (4.75 – 5 lbs/gal)

  • Temperature: 120 – 126 °C (250 – 260 °F)

  • Immersion Time: 2 - 15 Minutes.

  • Blackon SS-C is consumed and must be replenished as required.

Make Up
  1. Fill tank half full with cold water. Do not turn on heat.
  2. With the exhaust system turned on, add the Blackon SS-C salts to the cold water while stirring to dissolve the chemicals. Do not add all of the salts at once as this could cause a violent eruption.
  3. When all the salts have been added and dissolved, add cold water to bring the solution level to within 2 inches of the final desired level.
  4. Turn on the heat and stir as the temperature rises. Do not have the power turned on to the water inlet valve.
  5. When the solution reaches a boil, the motor operated valve may be turned on. If the boiling temperature exceeds 126°C, water may be added slowly to lower the temperature. If the boiling temperature is less than 126°C, additional Blackon SS-C salts can be added slowly to raise the boiling point or the solution may be allowed to boil to evaporate water and raise the boiling point. Adding salts, adding water or evaporating water is used to make the final adjustment of the solution to the desired operating level where it is then maintained.
Black Oxide Process:
  1. Clean in a alkaline soak cleaner.
  2. Rinse.
  3. Acid pickle.
  4. Rinse
  5. Blacken parts in Blackon SS-C.
  6. Rinse. Transfer time should be as short as possible to avoid the development of a red tint on the metal surface.
  7. Seal the finish in a water displacing solution.

The concentration of Blackon SS-C is maintained by the boiling point of the solution. The salts are mainly lost from the solution by drag out and must be replenished. Frequent additions of small amounts of salts will produce more uniform results than large amounts added less frequently. Water will be lost only by evaporation.

If the boiling point drops below 120 °C, salts are slowly added until the boiling point reaches 285°F. If the boiling point exceeds 126 °C water is slowly added until the boiling point is reduced and the heat is lowered to provide a gently rolling boil.

Salts are added only to raise the level of the tank or raise the boiling point. If the solution level falls below the desired working level, water is slowly added until the solution level reaches the desired point, and then the salts are slowly added to produce the desired boiling point.

Water must not be allowed to enter tank unless solution is boiling or is being stirred.

When salts are added to a Black Oxide solution they should be added slowly by sprinkling over the entire surface while stirring the solution. Large additions of salts should never be dumped into the solution as a violent eruption of the hot solution could occur.

Although the temperature of the solution can be maintained by manually adding water, an automatic indicating temperature controller is recommended for the safe addition of water. As water is evaporated, the boiling point will rise and the automatic temperature controller will replenish the water as needed on a continuous basis, maintaining the correct boiling point and concentration.

Water should only be added automatically to the solution when it is boiling so that the fresh water is rapidly and thoroughly dispersed throughout the solution from the boiling action. If water is added to the solution when it is not boiling, a violent eruption of the solution could occur. Stirring the solution is satisfactory if water is added manually when the solution is not boiling.

The bath should be periodically cleaned to remove the accumulation of sodium carbonate, iron oxide and soils at the bottom of the tank. The surface of the solution should also be periodically skimmed to remove hydrated iron oxide from the surface.

Sludge accumulating on the bottom of under fired gas heated tanks could lead to a violent eruption of the solution due to a sudden overheating from the insulating effect of the sludge. The sludge could also become overheated and suddenly crack, allowing water to penetrate below the sludge causing the sudden formation of steam and the violent eruption of the solution.

When heat is applied to a cold Black Oxide solution, the solution must be stirred until the operating temperature is reached to avoid overheating and the violent eruption of the solution.

Please note that the information above for this chemical is partial. Click the button below to request full technical information sheet.
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